|
KMID : 1059519880320050495
|
|
Journal of the Korean Chemical Society
1988 Volume.32 No. 5 p.495 ~ p.500
|
|
|
MO Interpretation for the trans Effect of Square Planar Type Pt(Ⅱ) Complexes
|
|
Park Byung-Kak
Lee Sang-Hyup
Yeo Hwhan-Jin
Cho Lee-Yeung
|
|
|
Abstract
|
|
|
|
The trans effect has been interpreted for a series of trans-[PtNH3Cl2L] (L = H2O, NH3, Cl-, Br-, I-, CH3 and PH3) and PtCl4-2 by means of our modified-EHMO method. The calculation shows that reduced overlap population(ROP) of Pt-N bond trans to L is decreased with a better trans director. That is, the trans effect has been found to be enhanced with a better trans director. Accordingly, it could be interpreted quantum chemically the trans effect for a general trans-PtTL2X complex.
|
|
|
KEYWORD
|
|
|
|
|
|
FullTexts / Linksout information
|
|
|
|
|
|
Listed journal information
|
|
|